ВУЗ: Не указан
Категория: Не указан
Дисциплина: Не указана
Добавлен: 30.07.2024
Просмотров: 313
Скачиваний: 0
B&%,0;& 4.1 (*+#$#,C!30!)
1 |
|
|
2 |
|
3 |
|
|
|
|
|
|
|
|
|
|
|
|
L<G |
|
|
|
|
|
Cu2! |
|
|
|
|
|
|
|
|
|||
|
D+!$'&+0"!,A3#! 6#"#G0/09!4(#! #(04,!30! #+7&309!4(0G '!K!4"' (OP- |
|
|||
|
#%,89!30! 4 $#%&'(&/0 #(04,0"!,!5), *!+!'#$ (#/*,!(43<G 4#!$03!305 /!$0 ' |
|
|||
• ;251.2 '!(. |
0#33#! 4#4"#-30!. )*+!$!,!30. 3! /!?&." 100-(+&"3<5 0:%<"#( Zn(II), Ni(II), |
[8] |
|||
|
|
|
|
|
|
|
Cd(II), 200-(+&"3<5 0:%<"#( |
Al(III), 100-(+&"3<5 0:%<"#( Pb(II), 20-(+&"3<5 |
|
||
|
0:%<"#( Cr(III) 0 Fe(III) *+0 4##"3#?!300 1Q1 |
|
|
||
|
|
|
|||
|
HFI Cu2+. =3&,0:0+8!/<5 +&4"'#+ 4/!?0'&." ' #"3#?!300 1:1 4 %86!+3</ |
|
|||
• 4"-"!(1.2 |
+&4"'#+#/, 4#$!+C&K0/ |
&;!"&" 3&"+0- (0,05 ), 8(48438. |
(04,#"8 (0,05 ), |
|
|
'!(. |
6"#+0$ 3&"+0- (2,0·10-2 |
), $,- 84"&3#',!30- *#4"#-33#5 0#33#5 40,< 0 +1, |
[2] |
||
|
/&4(0+#'&30Fe(III) 0 '#44"&3#',!3040,A3<G #(04,0"!,!5. |
!"#$ L+&3&. |
|
||
|
|
|
|||
|
Cu2+ -4!,!("0'3<5 E,!("+#$. D#"!3;0#/!"+09!4(#! (#/*,!(4#3#/!"+09!4(#! |
|
|||
• J8!51.2 '!(. |
"0"+#'&30! Cu 2! 0 Zn 2! . |
!?&.K!! ',0-30! Fe(III) /&4(0+8." %86!+3#5 |
|
||
3%/D'%1-52#$-, |
4/!4A., 4#$!+C&K!5 70$+#6"&,&" (&,0- 0 6"#+0$ 3&"+0-. |
|
[8] |
||
0"!-*'!(#8' |
|
|
|
|
|
|
|
|
|
|
|
93
94
B&%,0;& 4.1 (*+#$#,C!30!)
1 |
|
|
|
|
|
2 |
|
3 |
|
|
|
|
|
|
|
|
|
||
|
|
|
|
|
|
||||
• J8!51.2 '!(. |
!"#$ *+!$3&:3&9!3 $,- #*+!$!,!30- ' $0&*&:#3! (#3;!3"+&;05 0,06 – 635 |
|
|||||||
3%/D'%1-52#$-, |
/7/$/3 Cu 2! ' *+048"4"'00 100-(+&"3#7# 0:%<"(& Fe(III), Cr(III), 10-(+&"3#7# |
|
|||||||
0"!-*'!(#8' - |
0:%<"(& Pb(II) 0 1000-(+&"3#7# 0:%<"(& Ni(II), Zn(II), Cd(II). 2 (&9!4"'! |
[8] |
|||||||
|
|
|
|||||||
3%/D'%1-52#$-, |
/&4(0+8.K0G '!K!4"' *+0/!3-." NaF. |
|
|
||||||
'%11 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|||
M=N;@N> |
|
|
|
|
|
|
|||
NO |
|
|
|
|
|
|
|
|
|
3 |
|
|
|
|
|
|
|
||
|
|
|
|
|
|||||
|
|
|
D+#%8 &3&,0:0+8!/#5 '#$< 0 4"&3$&+"3<! +&4"'#+< 4/!?0'&." 4 +&'3</ |
|
|||||
|
|
|
#%N!/#/ +&4"'#+& $,- *#$&',!30- /!?&.K0G *+0/!4!5. !"#$ 7+&$80+#'#93#5 |
|
|||||
• 4-8D2'%& '!(% |
:&'040/#4"0. D+-/&- *#"!3;0#/!"+0-. |
0(+#*+#;!44#+3<5 0#3#/!+. !"#$ |
[5] |
||||||
|
|
|
|||||||
|
|
|
$#%&'#( S |
|
|
= 0,03 – 0,1. |
|
|
|
|
|
|
x |
|
|
||||
|
|
|
|
|
|
|
|||
|
|
|
|||||||
• J8!51.2 '!(., |
&4(0+#'&30! &30#33<G D=2 ''!$!30!/ E('0'&,!3"3#7# (#,09!4"'& |
|
|||||||
#!(2"O%P-2 4@) |
(&"0#33<G D=2. D+-/&- *#"!3;0#/!"+0-. |
!"#$ 7+&$80+#'#93#5 :&'040/#4"0. |
[5] |
||||||
|
|||||||||
|
|
|
|
|
|||||
• )!(. |
D+0 3!%#,A?#/ 4#$!+C&300 Cl -0#3#' %!: *#$7#"#'(0 *+#'#$-" #*+!$!,!30! |
|
|||||||
30"+&"-0#3#' ' '#$!, *+-/&- *#"!3;0#/!"+0-. |
[3] |
||||||||
|
|
|
|||||||
|
|
|
|
||||||
|
|
|
|
|
|
|
|
|
|
B&%,0;& 4.1 (*+#$#,C!30!)
1 |
|
|
|
|
|
2 |
|
|
3 |
||
|
|
|
|
|
|
|
|
|
|||
|
|
|
|
|
|
I(4"+&(;0- NO3 0: *+#%< +&4"'#+#/ CuSO4 $,- /&4(0+#'&30- HCO3 0 Cl–- |
[5] |
||||
|
|
|
|
|
0#3#'. 2,0-30! NO2 84"+&3-." $#%&',!30!/ 48,A6&/03#'#5 (04,#"< ' H2SO4, |
|
|||||
|
|
|
|
|
/!"#$ 7+&$80+#'#93#5 :&'040/#4"0 *+-/&- *#"!3;0#/!"+0-. |
|
|||||
|
|
|
|
|
|
1&'!4(8 '<48?!33#7# "#3(#0:/!,A9!33#7# #%+&:;& 4/!?0'&." 4 +&4"'#+#/ $,- |
[2] |
||||
|
|
|
|
|
|
|
|||||
• 4!5'. |
*#$&',!30- ',0-30- /!?&.K0G *+0/!4!5. F/!4A *!+!/!?0'&." 30 /03. 0 |
|
|||||||||
|
|
|
|
|
60,A"+8.", 84"&3&',0'&." 3!#%G#$0/<! :3&9!30- +1, 0#33#5 40,< 0 84"+&3-." |
|
|||||
|
|
|
|
|
/!?&.K!! ',0-30! Cl–, NO2 , CO32 |
0 |
#+7&309!4(0G (04,#". |
|
|||
|
|
|
|
|
|
0(+#*+#;!44#+3<5 0#3#/!+. !"#$ 7+&$80+#'#93#5 :&'040/#4"0. |
|
||||
|
|
|
|
|
|
|
|
|
|||
|
|
|
|
|
|
)*+!$!,-." #"$!,A3# NO3 0 48//8 NO3 0 NO2 |
*+0 +1 4-8. 10"+0"-0#3< |
|
|||
• 4!5'. - |
#(04,-." KMnO4 ' (04,#5 4+!$!. H:%<"#( MnO4 |
8$&,-." $!54"'0!/ MnSO4. |
[5] |
||||||||
#8!51.2 '!(. |
|
|
S |
|
|
|
|
|
|||
|
|
|
|
= 0,015 – 0,036. D+-/&- *#"!3;0#/!"+0-, /!"#$ 7+&$80+#'#93#5 :&'040/#4"0. |
|
||||||
x |
|
||||||||||
|
|
|
|
|
|
|
|
|
|
||
|
|
|
|
|
|
|
|
||||
M=N;@N> |
|
|
|
|
|
|
|
||||
NO |
|
- NO |
|
|
|
|
|
|
|
|
|
3 |
2 |
|
|
|
|
|
|
|
|||
|
|
|
|
|
|
|
|
|
|
|
|
95
96
B&%,0;& 4.1 (*+#$#,C!30!)
1 |
|
2 |
|
|
|
3 |
|
|
|
|
|
|
|
|
D#4,!$#'&"!,A3#! 0:/!+!30! *#"!3;0&,#' HFINO3 |
|
|
0 HFINO2 . >&49!" 4 |
|
|
|
*+0/!3!30!/ (#E660;0!3"#' 4!,!("0'3#4"0. H3"!+'&, #*+!$!,-!/<G |
|
||||
• JA2#D |
(#3;!3"+&;05 10–4–10–2 NO3 |
0 NO2 *+0 /#,A3#/ 4##"3#?!300 1:1. D+-/&- |
[5] |
|||
|
*#"!3;0#/!"+0-, /!"#$ 7+&$80+#'#93#5 :&'040/#4"0. S |
|
|
= 0,15. |
|
|
|
x |
|
||||
|
|
|
|
|
||
|
|
|
|
|
|
|
:EJ=<> @Q:N@ |
|
|
|
|
|
|
NOx |
|
|
|
|
|
|
|
|
|
||||
|
D#7,#K!30! +&4"'#+#/ R12>)4, 4#$!+C&K0/ 12)2. )*+!$!,!30! |
|
||||
• )!*(+, |
#%+&:#'&'?0G4NO3 -0#3#' |
/!"#$#/ *#"!3;0#/!"+09!4(#7# "0"+#'&30-. |
[5] |
|||
M8'4"'0"!,A3#4"A – 3·10–4%. |
|
|
|
|
||
|
|
|
|
|
|
|
|
|
|
|
|||
|
D#7,#K!30! +&4"'#+#/ N&)1, #(04,!30! $# NO3 |
4 *#/#KA. PbO2 ' |
|
|||
• ).,/!01.2 |
*#$(04,!33#/ +&4"'#+! Na2SO4. !"#$ 7+&$80+#'#93#5 :&'040/#4"0, /!"#$ |
[5] |
||||
3%*. NO - NO2 |
$#%&'#(. M8'4"'0"!,A3#4"A 150-200 /7//3 NO2. |
|
|
|
||
|
|
|
|
|||
|
|
|
|
|
|
|
B&%,0;& 4.1 (*+#$#,C!30!)
1 |
|
2 |
3 |
|
|
|
|
||
|
D+0/!40 #(40$#' &:#"& ' '#:$8G! #*+!$!,-." *+0 *#/#K0 E,!("+#$&, |
|
||
|
98'4"'0"!,A3#7# ( #(40$&/ &:#"&. B#93# 84"&3#',!33<5 #%N!/ &3&,0:0+8!/#7# |
|
||
• )!*(+, |
'#:$8G& *+#(&90'&." 4# 4(#+#4"A. 2,//03 9!+!: *#7,#"0"!,A3#! 84"+#54"'#, |
[2] |
||
:&*#,3!33#! +&4"'#+#/, 4#$!+C&K0/ N&12>)4, N&21>)4, HgCl2, KCl, K2Cr2O7. |
||||
|
|
|||
|
R *#,89!33#/8 +&4"'#+8 $#%&',-." ' 4##"3#?!300 1:10 (04,#"3<5 %86!+3<5 |
|
||
|
+&4"'#+. |
0(+#*+#;!44#+3<5 0#3#/!+. !"#$ 7+&$80+#'#93#5 :&'040/#4"0. |
|
|
|
|
|
||
|
HFINO3 . B#93# 84"&3#',!33<5 #%N!/ &3&,0:0+8!/#7# 7&:& *+#(&90'&." 4 |
|
||
|
*#/#KA. '&(88/3#7# 3&4#4& 9!+!: 3&7+!"8. $# 190ºF "+8%(8, :&*#,3!338. |
|
||
|
(+04"&,,09!4(0/ PbO2. F#$!+C0/#! "+8%(0 0:',!(&.", 4/!?0'&." 4 "'!+$</ |
|
||
• <.A!'.2 3%*. |
PbF2 0 $04"0,0+#'&33#5 '#$#5 0 3&7+!'&." 30 /03. *+0 100ºF. F84*!3:0. |
[3] |
||
|
#G,&C$&.", ;!3"+06870+8.". )"%0+&." &,0('#"38. 9&4"A 3&$#4&$#93#5 |
|
||
|
C0$(#4"0 0 *+0%&',-." ( 3!5 +&4"'#+ 6#46&"& 3&"+0-. 0(+#*+#;!44#+3<5 |
|
||
|
0#3#/!+. |
!"#$ 7+&$80+#'#93#5 :&'040/#4"0. |
|
|
|
|
|
|
|
;:<@M=<> |
|
|
|
|
SCN |
|
|
|
|
|
|
|
|
|
97