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Z(4&3, 3,-,,
<$%*&$*%- 1&*-
Analytical Chemistry (-. Web-c/1'& http://pubs. acs.org/journals/ancham
Fresenius Journal of Analytical Chemistry: http://link.springer.de
G=5/.)$/'&%>+9& 45)?5/--9: http//www. scimedia.com
The Society for Electroanalytical Chemistry
(http://www.access.ch/ise/welcome.html)
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• P%/()$ U.T., X&?,+ @.P., J;*+,<7/# @.Q. Q;%>',(&+()5+9& (,('&-9 ',4/ D%&7'5)++91 #.97 – +)$9& $).-)0+)(', ().*/+,# , 45,-&+&+,# 3,-,6&(7,3 (&+()5)$//Z(4&3, 3,-,,, 2006. - O.75, [.2. -
!.142 - 149.
•H;%/4,+ @. ., Q/'&5)$/ F.@., H;%/4,+/ F.T.
O$&5*)7)+'/7'+9& 4)'&+<,)-&'5,6&(7,& (&+()59 ( 4%/(',B,<,5)$/++9-, 4)%,$,+,%3%)5,*+9-, -&-=5/+/-,// V/$)*(7/# %/=)5/')5,#. I,/?+)(',7/ -/'&5,/%)$. - 2002. - O.68, [12. - !.3-11.
• \.J. M/.&%>. "%&7'5)*+)/7',$+9& $&A&('$/ +/ )(+)$& ,)++93 /(()<,/')$ ( 7/',)++9-, 75/(,'&%#-, $ ,)+)-&'5,,// S;5+. /+/%,'.
3,-,,. – 2002. – O. 57, [12. – !. 1252 – 1256.
• !.P. R/5,')+)$. )+)(&%&7',$+9& D%&7'5)*9 *%# )45&*&%&+,# %&7/5('$&++93 $&A&('$// Z(4&3, 3,-,,. – 2007. – O.76, [4. – !.398 – 431.
201
202
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1 |
2 |
3 |
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4 |
5 |
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6 |
7 |
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Ag ! , S 2" |
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1-10-7 |
Q&2/8' (%&*9 ,)+/ Hg 2! |
2-8 |
0-80 |
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1-10-17 |
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pAg |
Ag2 S |
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(=;B&5- |
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+91 |
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5/('$)5) |
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pCd |
CdS |
Ag ! , Hg 2! , |
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10-1-10-6 |
Pb2! ~1; Zn2! , Co2! , Ni2! ~10-3 |
1-8 |
0-50 |
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Cd 2! |
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pCu |
CuS |
Ag ! , Hg 2! , |
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1-10-6 |
Pb2! , Cd 2! , Co2! , Ni2! , Zn2! ~10-3 |
1-14 |
0-50 |
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Cu 2! |
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pHg |
AgI |
Ag ! , Hg 2! |
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10-4-10-6 |
Cl " , Br " ~10-2 |
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1-6 |
0-50 |
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pPb |
PbS |
Ag ! , Hg 2! , |
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10-1-10-6 |
Fe2! ~102; Cd 2! ~1 |
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2-7 |
0-50 |
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Pb2! |
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pS |
Ag2 S |
Ag ! , S 2" |
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1-10-7 |
Q&2/8' (%&*9 ,)+)$ Hg 2! |
13-14 |
0-50 |
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Ag ! , S 2" , |
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1-5·10-5 |
CN " ~400; I " ~86,5; S2O32" ~60; |
2-12 |
0-50 |
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pCl |
AgCl |
I " , Br " , |
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Br " ~ 1,2; OH " ~2·10-2; |
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Cl " |
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SO42" ~6·10-3 |
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O/=%,</ 1 ()7)+6/+,&)
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2 |
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4 |
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6 |
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pI |
AgI |
Ag ! , S 2" , |
1-5·10-8 |
SO42" ~1; CN " ~0,34 |
3-12 |
0-50 |
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I " , Br " |
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pCN |
AgI |
Ag ! , S 2" , |
10-2-10-6 |
I " , SO42" ~3 |
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11-13 |
0-50 |
I " , CN " |
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pSCN |
AgSCN |
Ag ! , S 2" , |
1-10-5 |
I " ~70; Br " ~1 |
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2-12 |
0-50 |
I " , Br " |
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H)+<&+- |
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G(+)$+/# |
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+,#, " |
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1 |
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3 |
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• Ag2 S |
Ag ! , S 2" |
1-10-7; |
Cu 2! ~10-6; Pb2! ~10-10; -&2/8' |
2-9 |
-5-100 |
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4)%,75,('/%%,6&(7,1 |
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<10-23 |
(%&*9 ,)+/ Hg 2! ; 4)(%& |
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(45&(()$/++91) |
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+91 |
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pAg |
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1-10-6 |
4)$&53+)(', |
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Ag ! , S 2" |
Cu 2! ~10-5; Pb2! ~10-6; H ! ~10-7; |
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-&2/8' ,)+9 Hg 2! |
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203
204
O/=%,</ 2 (45)*)%0&+,&)
1 |
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2 |
3 |
4 |
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5 |
6 |
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•#uS |
Ag2 S |
Ag ! , S 2" , |
1-10-8; |
Fe3! ~10; Cu2! ~1; ,)+9 Cl " , Br " |
0-14 |
0-100 |
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Cu 2! , Hg 2! |
<10 |
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(=;B&5- |
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pCu |
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1-10-6; |
Pb2! ~10-4; Cd 2! ~10-5; Cu ! ~ 1011; |
0-14 |
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Cu 2! , Cu ! |
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Ag ! ~106; Hg 2! ~104 |
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(=;B&5- |
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5/('$)5) |
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CdS Ag2 S |
Ag ! , S 2" , |
0,1-10-7; |
Fe2! , Tl ! ~120; Pb2! ~6; Mn2! ~3; |
1-14 |
0-100 |
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pCd |
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Cu 2! , Cd 2! |
<10-10 |
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5/('$)5) |
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PbS Ag2 S |
Ag ! , S 2" , |
0,1-10-7; |
Fe3! , Cd 2! ~1; ,)+9 Ag ! , Hg 2! , |
2-14 |
0-100 |
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Cu 2! , Pb2! |
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Cu 2! *)%0+9 )'(;'('$)$/'> |
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(=;B&5- |
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+91 |
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pPb |
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5/('$)5) |
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205
O/=%,</ 2 (45)*)%0&+,&)
1 |
2 |
3 |
4 |
5 |
6 |
7 |
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• Ag2 S |
Ag ! , S 2" |
1-10-6; |
:)(%& *%,'&%>+)?) 7)+'/7'/ ( |
13-14 |
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4)%,75,('/%%,6&(7,1 |
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<10-23 |
5/('$)5/-,, ()*&50/A,-, Hg 2! , |
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pS |
(45&(()$/++91) |
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+91 |
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5/('$)5) |
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•-)+)75,('/%%,6&(7,1 |
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Cu 2! ~10-5; Pb2! ~10-6 |
- |
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pF |
LaF3 |
F " |
1-10-6 |
OH " ~0,1; Cl " , Br " , I " , NO3" , |
4-8 |
-5-100 |
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-)+)75,('/%%,6&(7,1 |
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CO32" , SO42" ~10-3 |
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AgCl Ag2 S |
Ag ! , Cl " |
1-10-5 |
Br " ~102; I " ~10-6; OH " ~10-2; |
2-12 |
0-100 |
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pCl |
45&(()$/++/# (-&(> |
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CN " ~10-4; ,)+9 S 2" *)%0+9 |
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)'(;'('$)$/'> |
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• AgCl |
- |
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CN " ~8; Br " , I " ~2; NH3 ~10-1; |
0-14 |
-5-60 |
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pCl |
-)+)75,('/%%,6&(7,1 |
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OH " ~10-2 |
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• AgCl (Philips; Schott |
- |
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CN " ~4·102; I " ~102; S2O32" ~60; |
1-10 |
0-100 |
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ond Gen,; Tacussel) |
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Br " ~1; OH " ~ 10-2; CO32" ~10-3 |
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pBr |
• AgBr Ag2 S |
Ag ! , Br " |
1-5·10-6 |
I " ~5·103; CN " ~102; Cl " ~5·10-3; |
2-12 |
0-100 |
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45&(()$/++/# (-&(> |
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OH " ~10-5; ,)+9 S 2" *)%0+9 |
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)'(;'('$)$/'> |
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• AgBr |
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I " ~2; CN " ~1; Cl " ~5·10-3; |
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-)+)75,('/%%,6&(7,1 |
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0-14 |
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NH3 ~4·10-3; OH " ~10-4 |
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• AgBr (Philips; Schott |
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1-10-6 |
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1-11 |
0-50 |
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CN " ~25; I " ~20; S2O32" ~1,5; |
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Cl " ~6·10-3; CO32" ~2·10-3; |
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OH " ~10-3 |
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206
O/=%,</ 2 ()7)+6/+,&)
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2 |
3 |
4 |
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5 |
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6 |
7 |
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• AgI Ag2 S |
Ag ! , S 2" , |
1-5·10-8 |
S 2" ~30; S2O32" ~3·10-2; CN " ~10-2; |
0-14 |
0-80 |
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45&(()$/++/# (-&(> |
I " |
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Br " , SCN " ~10-4; NH3 ~3·10-5; |
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pI |
• AgI (Crytur; Pnilips; |
Ag ! , I " |
- |
Cl " ~10-6; OH " ~10-7 |
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1-12 |
0-50 |
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CN " ~0,34; CrO42" ~4·10-3; |
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Schott and Gen.; |
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2" |
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Tacussel) |
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S2O3 |
~7·10 |
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Cl " ~6·10-6; ,)+9 S 2" |
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AgSCN Ag2 S |
Ag ! , SCN " |
1-5·10-6 |
I " ~103; Br " , CN " , S2O32" ~102; |
2-12 |
0-95 |
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pSCN |
45&(()$/++/# (-&(> |
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NH3 ~10; Cl " ~10-1; OH " ~10-2; |
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,)+9 S 2" |
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• AgI Ag |
2 |
S |
Ag ! , I " , |
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I " ~102; Br " ~10-4; Cl " ~10-6; |
11-13 |
0-80 |
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OH " ~10-8; ,)+9 S 2" |
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pCN |
45&(()$/++/# (-&(> |
CN " |
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• AgI (Crytur; Pnilips; |
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I " ~3; CrO42" ~10-2; S2O32" ~10-3; |
10-12 |
0-50 |
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pI |
Schott and Gen.; |
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#O32" , Br " ~10-4; Cl " ~10-5 |
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Tacussel) |
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