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2.C? .0. M#%# # A 8 # ? "$. — .: , 1982.

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CUGATE2 {MN}

D # # " #" & " / " / &*$# # , & A#- > Mn, & @ " $"$# >8# 8 # & 8# ?& A " # &* >" #8 % # 8 8$> 8 A # A $# , - & A# " *@ # $& # # " > 8 #" && .

D # # CuGaTe2 — # 8 A # , # A !#%# " # " /" ?> E* $& > 8 #" & " # ? % [1].

' / ? 8# ?> >$& > -8 A #-% " > (– ) #""& # $# 8$ ` = 290 "$8 Bruker Avance-400. % " > "$> ?&@ "* " 106,14 ( & 63Cu) # 96 ( & 69Ga). "$#8 &* > "$> – 63Cu # 69Ga ? %- A " # # CuGaTe2 " " #% &* A $# , ! 8 A$& " #%$# / #8# " A " #A , # E# A "$, $ - " & @= A " ? / ? > $&* E# > $>.

D & >, ? "& & > $8# (±3/2- ±1/2) # % # @=# % " $&* > % #8 /" #/ $A $, % "* "& ?>8# $ # "# " #, # $# # $# " # % 8 > # "$& > - " 8 #$% 300 . A# # Mn $# #& % # &* 8 " # #@ # "# " # "#A & – 63Cu # E# #@ #/. D$ - > – 69Ga & A# > Mn ? % $" & @ " ? / # @ "#88 # @ #@ ? % /-? " >, %> 8 & % # " > $&* / " %#. ? >/ 8# # "$ -– %> $#" " # #""& > " # # ? &*- E A %? " # A& " %# " > # ?%#$%# #/ Cu, # $%# #/ Ga. D& 8 # *, >" - # " ?" > ! ? % 8 " # ## CuGaTe2,, " % " #% &* >8 & # 8 " # 8 ##, # # & " " !- 8 A # >8 8 % #8 /" # & A# > ? % CuGaTe2{Mn}, 8 A ?> * $& # &* >8# ! 8#, $#- =#8# % # &* 8 E# #@ % " > #/, $" &* - $&* > $" > "*8 " # &* > % 8, # 8 A #- >8 8 8 8, & % >8 %& #" & " / E #.

< & > % &* > > & ? & A& ? A $#8 # !#%#- " # $"" , $#" =# #""& > #" && .

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1. Marin G., Perez G.S., Marcano G. et al. // J. Phys. Chem. Solids. 2003.64. 1869.

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2010.

2.Electrical characterization of hydroxyapatite-based bioceramics, University of Bath / J.P. Gittings, C.R. Bowen, A.C.E. Dent et al. 2008.

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< & > "$> – 63Cu ? % CuxAlO2 " " #% / % " / ##, " " @= / # " / #" && A !#- " / $%# ## 8 8 # " " # # . < & > C "$ - #8 ! 8> ## – 63Cu ?> $" & > # " 88> #/ A "" / ! 8> Cu-1 # Cu-2. D " & @= @ "$&* / ## Cu-1 8 " # " # &* ? & $>8 " >8 ?& " 8 # $ $& # *, E# # C / ##, # & " #""& > ? % , ? "& & " ?" >8# ! 8# "- # # CuAlO2. #8# ! 8# 8 A ?> * 8$& ">, &@ @=# #" > ! > — 8 &@8# # $%# ## 8 # AlCu # 8 % &* > 8 #"& Oi, . . (AlCu··2O¶¶i )¶¶. D " = " # 8 # ! > 8$& " " %> " > $#8 " * " #- # CuAlO2 [1, 2]. D " & @= "$&* / ## Cu-2, $ - # #8 8 , " % " % " >8# 8#, "$& >8# " #- &* ? & %$> ?& " #" & " / " >. # ?& " # 8 A % # * ?& A " >8 $# 8 # ! 8 $# "#" 8 $ #$ #" && .

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1.! $"$# A 8 C& # " A " # # CuAlO2 8- 8 A $&* A % " Cu / '. . # , . . ?#? & , . . • &*A# # . // M#%# # # $&$# . 2012. . 46. '>$. 9.

2.Ingram B.J., Gonzalez G.B., Mason T.O. et al// Chem. Mater. 2004.

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1.' C& # " # 8 E# / .<. $>& , U. . & , '.<. % # , U.M. . 2- #% . — .: A 8#% , 1993.

2.Vimala Shekar. Effect of fiber architecture on properties of pultruded composites. College of Engineering and Mineral Resources, West Virginia University. 2007.

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